However,ifyourwifeisalsoentitledtofamilybenefitsbecauseshe'sworkinginSlovenia,theauthoritieswillworkoutwhoshouldpaythem;youwon'tgetfullbenefitsfrommorethanonecountry.
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However, if your wife is also entitled to family benefits because she's working in Slovenia, the authorities will work out who should pay them; you won't get full benefits from more than one country.